The problem is with any puller on a cast iron pulley, in such a situation is unless your uber carful your very likely to break a piece out of the pulley if you persist as you will not get any warning.
A far better approach (which has worked for me), is to drill and tap two extractor bolt holes in the hub of the pulley, using long series taps and drills, and use these to pull the pulley off the shaft.
This will take time, but is still easier than breaking the pulley and having to get it welded up afterwards.