A modern head gasket will easily hold high pressures. However, the castings on my Listeroid are such poor quality and so thin in spots, I can't imagine they'd hold up long under 100PSI use. I do run a 13PSI cap on my radiator and it does boil over from time to time, with no water in the oil.
However, I did install new O rings on the liners and I used DC-4 silicone O ring lube to install them.