It is not as easy as I would have like it to be....
Once you have got the rear bearing off (this is the easier one to remove but you will either have to strike it off or use a hydraulic puller), unsolder the slipring fly leads from the rotor copper. Cut and remove the lacquered fabric that holds the flyleads close to the rotor and then put a long reach puller on the slipring assembly. They are pressed on but I am convinced that some adhesive is also used.
Removing the slipring also destroyed it in my case - so maybe you could just hacksaw it off.
The splines on the rotor where the slipring assembly sit will need to be cleaned up before pressing a new one on.
Pressing a new on on is easy if you can line it up square to start with. Use an annular drift to push it all the way home before remaking the soldered connections and wire-ties to the rotor shaft.
The reason that I removed my slipring assembly was that it was not square and caused the brushes to oscillate and mis track the brass rings. After I replaced the assembly the new one was still not square but a little bit better than the original one. The brushes still oscillate and mis track but this does not appear to be a problem in use.
If I had your problem today, I would not, now, replace the slipring assembly unitil I had tried to repair the original.
So what is wrong with one slip ring being slightly smaller than the other ? If you were so worried about the rings being different diameters, you could also remove both brass rings (in situ) and turn up some new ones to slide onto the insulator whilst it is still on the shaft.
I hope this helps.
Regards,
Ian