Plenty of decent DIY electrolysis setups using stainless steel screens; the only bugger is the storage. It is a pity to not be able to use the oxygen, since as you noted, it's a hell of a fuel booster, but like you, I found Brown's gas something to be be very careful around. It's shockingly explosive. Isolation of oxygen at the plates seems to be the preferred method, as you noted, Glort. You need a buck converter to dial down PV voltage or your efficiency will be poor and you'll boil off your electrolyte. If you need more gas production with reasonable efficiency it must be done by adding a lot more cathode and anode area.
I did some experimenting with hydrogen when I was considering my off grid homestead plans. You can make it quite cheaply if you have access to scrap aluminum, just add lye-water solution but be prepared to deal with the substantial heat generated. It is a fabulous co-generator of heat plus hydrogen with relatively little aluminum consumed. It can generate gas at moderate pressure without the need for a pump if your vessel can handle it as well as the lye water.
To use it in a conventional gas burner at 10" of water pressure, you must plug up roughly 2/3 of the holes and surround the propane burner element with stainless steel wool to act as a catalyst to lower the burn temperature. With the stainless steel wool you can see the flame as bluish. You don't want air mixed in so stock gas-air mixers must be sealed well with foil tape and silicone caulk or lighting the burner will be dangerously explosive. It did work, but for myself I found that the higher burning temperatures caused more oxides from air gasses, and I didn't find open hydrogen burning the odorless healthy panacea I was hoping for. (I did that testing with lab grade hydrogen.) There will be similar issues to work out with it's use in IC engines, I expect.
I did find that the modifications for burning hydrogen instead of LP or Methane were manageable, though sadly, it could not be a single burner- dual fuel setup.