FWIW I just un-siezed an old 3/1 that had been out in the weather with the ports exposed for at least ten years.
Took the head off, wiped/scraped all the crud out of the barrel above the piston, sprayed a bit of INOX/CRC around the edges of the cylinder and then heated gently with a propane torch until watery, rusty gunge started to bubble up around the edges - no big temperature rise on the cast piston you could still put your hand on it
Wiped that bubbled-up crud away and sprayed some more INOX around the edges and watched it fizz satisfyingly (is that a word?) and left it to cool for a few minutes then heated again.
Did that four or five times then tapped the piston with a bit of wood and a hammer until it started to move
After that it was just a matter of more INOX, patience and a pair of pipe tongs on the crankshaft.
FWIW it has been my experience of many years that heating judiciously, allowing to cool, and application of a penetrant will loosen almost anything.
Cheers