Short of a nameplate, and without running the machine, I can think of only two ways. First would be to count the number of stator main output leads:
If it has -
12 leads - 3 phase
10 leads - 3 phase
9 leads - 3 phase
6 leads - 3 phase
4 leads - could be either 3 or single phase - let us know how they are marked
3 leads - could be either – again, how are they marked?
2 leads - single phase
The second way to tell a single phase from a 3 phase is to inspect the stator windings from one of the ends of the machine. If they appear to be essentially uniformly spread around the circumference of the stator, it’s probably 3 phase. If there appear to be a pair of ‘gaps’ in the windings 180 degrees apart, it’s single phase.
Neither way is 100 % certain - tell us more about what you have.
If the machine can be spun up, and the field energized, it's also possible to tell by making voltage measurements across the output leads, but I'm not gonna take the time to explain that until I get more info about what you have...